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@Ukbaz,

for 1.7 just add the following code in the template themes/yourtheme/templates/catalog/product.tpl where you want the button to appear.

	<div class="contact">
		<a class="btn btn-primary add-to-cart" href="{$urls.pages.contact}">{l s='Contact us' d='Shop.Theme.Catalog'}</a>
	</div>

And then add css style for the div .contact if needed or change the add-to-cart style if you want a different style rendering for the button.

ie:

#product .contact {
    padding-top: 25px;
}

Don't forget also to translate the sentence "Contact us" if you use a different language than english.

@Ukbaz,

for 1.7 just add the following code in the template themes/yourtheme/templates/catalog/product.tpl where you want the button to appear.

	<div class="contact">
		<a class="btn btn-primary add-to-cart" href="{$urls.pages.contact}">{l s='Contact us' d='Shop.Theme.Catalog'}</a>
	</div>

And then add css style for the div .contact if needed or change the add-to-cart style if you want a different style rendering.

ie:

#product .contact {
    padding-top: 25px;
}